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O460 ORDINANCE NO. 460 AN ORDINANCE OF THE CITY OF KENNEDALE AMENDING ORDINANCE NO. 417, SECTION 9, ADOPTING THE 2006 INTERNATIONAL FIRE CODE; PROVIDING FOR THE ADOPTION AND INCORPORATION OF APPENDICES B THROUGH G OF THE 2006 INTERNATIONAL FIRE CODE; PROVIDING FOR RECORDING OF THE CODE AS A PUBLIC RECORD; PROVIDING FOR THE ISSUANCE OF PERMITS AND COLLECTION OF FEES THEREFOR; PROVIDING THAT THIS ORDINANCE SHALL BE CUMULATIVE OF ALL ORDINANCES; PROVIDING A SEVERABILITY CLAUSE; PROVIDING FOR A PENALTY FOR VIOLATIONS; PROVIDING A SAVINGS CLAUSE; PROVIDING FOR PUBLICATION IN PAMPHLET FORM; PROVIDING FOR PUBLICATION IN THE OFFICIAL NEWSPAPER; AND PROVIDING AN EFFECTIVE DATE. WHEREAS, the City of Kennedale is a home rule city acting under its charter adopted by the electorate pursuant to Article XI, Section 5 of the Texas Constitution and Chapter 9 of the Local Government Code; and WHEREAS, the City Council of the City of Kennedale adopted the 2006 Edition of the International Fire Code; and WHEREAS, the City Council now desires to adopt specific appendices to the 2006 Edition of the International Fire Code. NOW, THEREFORE, BE IT ORDAINED BY THE CITY COUNCIL OF THE CITY OF KENNEDALE, TEXAS: SECTION 1. ADOPTION OF APPENDICES B THROUGH G TO THE 2006 INTERNATIONAL FIRE CODE The 2006 Edition of the International Fire Code, as adopted, is hereby amended by adoption of those local Appendices B through G shown on Exhibit "A" attached hereto. Page 1 of 4 SECTION 2. MAINTENANCE OF CODES AS PUBLIC RECORDS The material contained in Exhibit "A" to this ordinance, although fully adopted and incorporated by reference, shall not be included in the formal municipal codification of ordinances. The material contained in Exhibit "A" shall instead by maintained as a public record in the office of the City Secretary, Building Official, Fire Marshal, and Library. These exhibits will be available for public inspection and copying during regular business hours. The purpose of maintaining these records separate and apart from the municipal codification is to avoid the inclusion of detailed technical construction materials, subject to frequent change, which would unreasonably lengthen the code. SECTION 3. ADDITIONAL LOCAL AMENDMENTS CONTEMPLATED The City of Kennedale may from time to time determine that additional local modifications to the 2006 Edition of the International Fire Code are necessary and appropriate to meet the unique building needs of the City of Kennedale. To effectuate modifications, the city council may enact individual ordinances amending this ordinance fully setting forth the change to be made in the specific code. Such subsequent amendments shall be consolidated as an exhibit to this ordinance, and shall be maintained as a public record in the office of the city secretary. SECTION 4. PERMITS AND FEES The codes adopted herein provide for the issuance of certain permits and the collection of fees therefore. The fees shall be established by the City's schedule of fees. SECTION 5. PROVISIONS CUMULATIVE BUT CONFLICTING ORDINANCES REPEALED This Ordinance shall be cumulative of all provisions of all existing ordinances and of the Code of Ordinances of the City of Kennedale, Texas, as amended, except where the provisions of this ordinance are in direct conflict with the provisions of such existing ordinances and code, in which event the conflicting provisions of such ordinances and Code are hereby repealed. SECTION 6. PROVISIONS SEVERABLE It is hereby declared to be the intention of the City Council that the phrases, clauses, sentences, paragraphs and sections of this Ordinance are severable, and if any phrase, Page 2 of 4 clause, sentence, paragraph or section of this Ordinance shall be declared unconstitutional by the valid judgment or decree of any court of competent jurisdiction, such unconstitutionality shall not affect any of the remaining, phrase, clauses, sentences, paragraphs or sections of this Ordinance since the same would have been enacted by the City Council without incorporation in this Ordinance of any such unconstitutional phrase, clause, sentence, paragraph or section. SECTION 7. PENALTY Any person, firm or corporation who violates, disobeys, omits, neglects or refuses to comply with or who resists the enforcement of any of the provisions of this Ordinance shall be fined no more than Two Thousand Dollars and no cents ($2,000.00) for all violations involving zoning, fire safety or public health and sanitation, including dumping or refuse, and shall be fined not more than Five Hundred Dollars and no cents ($500.00) for all other violations of this Ordinance. Each day that a violation is permitted to exist shall constitute a separate offense. SECTION 8. PREVIOUSLY ACCRUING RIGHTS AND REMEDIES SAVED All rights and remedies of the City of Kennedale, Texas, are expressly saved as to any and all violations of the provisions of the Building Code, Residential Code, Electrical Code, Energy Code, Fuel Gas Code, Mechanical Code, Plumbing Code, Existing Building Code, Property Maintenance Code, or any other ordinances affecting such codes which have accrued at the time of the effective date of this Ordinance; and, as to such accrued violations and all pending litigation, both civil and criminal, whether pending in court or not, under such ordinances same shall not be affected by this Ordinance but may be prosecuted until final disposition by the courts. SECTION 9. PUBLICATION The City Secretary of the City of Kennedale is hereby directed to publish in the official newspaper of the City of Kennedale, the caption, penalty clause, publication clause, and effective date clause of this ordinance in accordance with Section 52.013(b) of the Local Government Code. SECTION 10. PUBLICATION IN PAMPHLET FORM The City Secretary of the City of Kennedale is hereby authorized to publish this ordinance in book or pamphlet form for general distribution among the public, and the operative provisions of this ordinance as so published shall be admissible in evidence in all courts without further proof than the production thereof. Page 3 of 4 SECTION 11. EFFECTIVE DATE This Ordinance shall be in full force and effect form and after its passage and publication as provided by law, and it is so ordained. PASSED AND APPROVED ON THIS 12 DAY OF AUGUST 2010. •� f KE ' N APPROVED: .• ;(0:-.., 4 '• 1 ?).1ya" ii{,/fAkitelic7r MAYOR, BRYAN LANKHORST o r KATHY TT 0 RIER, CITY SECRETARY APPROVED TOAS TO FORM: 0- 01---1/4...-- WAYNE K. OLSON, CITY ATTORNEY Page 4 of 4 APPENDIX B FIRE -FLOW REQUIREMENTS FOR BUILDINGS The provisions contained in this appendix are not mandatory unless specifically referenced in the adopting ordinance. SECTION B101 B1043 Type IA and Type IB construction. The fire - flow cal - GENERAL culation area of buildings constructed of Type IA and Type IB construction shall be the area of the three largest successive B101.1 Scope. The procedure for determining fire -flow floors. requirements for buildings or portions of buildings hereafter constructed shall be in accordance with this appendix. This Exception: Fire -flow calculation area for open parking appendix does not apply to structures other than buildings. garages shall be determined by the area of the largest floor. SECTION B102 DEFINITIONS B102.1 Definitions. For the purpose of this appendix, certain SECTION B105 terms are defined as follows: FIRE - FLOW REQUIREMENTS FOR BUILDINGS FIRE - FLOW. The flow rate of a water supply, measured at 20 B105.1 One and two - family dwellings. The minimum pounds per square inch (psi) (138 kPa) residual pressure, that is fire -flow requirements for one- and two - family dwellings hav- available for fire fighting. ing a fire -flow calculation area which does not exceed 3,600 FIRE - FLOW CALCULATION AREA. The floor area, in square feet (344.5 m shall be 1,000 gallons per minute square feet (m used to determine the required fire flow. (3785.4 L /min). Fire -flow and flow duration for dwellings hav- s q ing a fire -flow calculation area in excess of 3,600 square feet (344.5 m shall not be less than that specified in Table B105.1. SECTION B103 Exception: A reduction in required fire flow of 50 percent, MODIFICATIONS as approved, is allowed when the building is provided with B103.1 Decreases. The fire chief is authorized to reduce the an approved automatic sprinkler system. fire -flow requirements for isolated buildings or a group of buildings in rural areas or small communities where the devel- B105.2 Buildings other than one and two - family dwellings. i opment of full fire -flow requirements is impractical. The minimum and flow duration for buildings other fire-flow g B103.2 Increases. The fire chief is authorized to increase the than one- and two-family dwellings shall be as specified in fire -flow requirements where conditions indicate an unusual Table B105.1. susceptibility to group fires or conflagrations. An increase Exception: A reduction in required fire -flow of up to 75 shall not be more than twice that required for the building under percent, as approved, is allowed when the building is pro consideration. vided with an approved automatic sprinkler system installed B103.3 Areas without water supply systems. For informa- in accordance with Section 903.3.1.1 or 903.3.1.2. The tion regarding water supplies for fire - fighting purposes in rural resulting fire -flow shall not be less than 1,500 gallons per and suburban areas in which adequate and reliable water sup - minute (5678 L/min) for the prescribed duration as speci- ply systems do not exist, the fire code official is authorized to fied in Table B105.1. utilize NFPA 1142 or the International Wildland -Urban Inter- face Code. SECTION B104 SECTION B106 FIRE -FLOW CALCULATION AREA REFERENCED STANDARDS B104.1 General. The fire -flow calculation area shall be the ICC IBC International Building Code B104.2, total floor area of all floor levels within the exterior walls, and Table B105.1 under the horizontal projections of the roof of a building, ICC IWUIC International Wildland- B103.3 except as modified in Section B104.3. Urban Interface Code B104.2 Area separation. Portions of buildings which are sep- NFPA 1142 Standard on Water Supplies for B103.3 arated by fire walls without openings, constructed in accor- Suburban and Rural Fire Fighting dance with the International Building Code, are allowed to be considered as separate fire -flow calculation areas. 2006 INTERNATIONAL FIRE CODE® 393 APPENDIX B TABLE 8105.1 MINIMUM REQUIRED FIRE -FLOW AND FLOW DURATION FOR BUILDINGS' FIRE -FLOW CALCULATION AREA (square feet) FIRE -FLOW FLOW DURATION Type IA and IB Type IIA and IllA Type IV and V -A Type IIB and IIIB Type V -B (gallons per minute) (hours) 0- 22,700 0- 12,700 0 -8,200 0 -5,900 0 -3,600 1,500 22,701- 30,200 12,701- 17,000 8,201- 10,900 5,901 -7,900 3,601 -4,800 1,750 30,201- 38,700 17,001- 21,800 10,901 - 12,900 7,901 -9,800 4,801 -6,200 2,000 2 38,701- 48,300 21,801- 24,200 12,901 - 17,400 9,801 - 12,600 6,201 -7,700 2,250 48,301 - 59,000 24,201- 33,200 17,401- 21,300 12,601- 15,400 7,701 -9,400 2,500 59,001- 70,900 33,201- 39,700 21,301- 25,500 15,401- 18,400 9,401 - 11,300 2,750 70,901- 83,700 39,701 - 47,100 25,501- 30,100 18,401- 21,800 11,301- 13,400 3,000 83,701- 97,700 47,101 - 54,900 30,101- 35,200 21,801 - 25,900 13,401 - 15,600 3,250 3 97,701 - 112,700 54,901- 63,400 35,201- 40,600 25,901- 29,300 15,601- 18,000 3,500 112,701- 128,700 63,401- 72,400 40,601- 46,400 29,301 - 33,500 18,001- 20,600 3,750 128,701 - 145,900 72,401- 82,100 46,401 - 52,500 33,501- 37,900 20,601- 23,300 4,000 145,901- 164,200 82,101- 92,400 52,501 - 59,100 37,901- 42,700 23,301- 26,300 4,250 164,201 - 183,400 92,401 - 103,100 59,101- 66,000 42,701- 47,700 26,301- 29,300 4,500 183,401- 203,700 103,101- 114,600 66,001- 73,300 47,701 - 53,000 29,301- 32,600 4,750 203,701 - 225,200 114,601- 126,700 73,301- 81,100 53,001 - 58,600 32,601 - 36,000 5,000 225,201- 247,700 126,701- 139,400 81,101- 89,200 58,601- 65,400 36,001- 39,600 5,250 247,701 - 271,200 139,401- 152,600 89,201- 97,700 65,401- 70,600 39,601- 43,400 5,500 271,201- 295,900 152,601 - 166,500 97,701 - 106,500 70,601- 77,000 43,401- 47,400 5,750 295,901- Greater 166,501- Greater 106,501- 115,800 77,001- 83,700 47,401 - 51,500 6,000 4 115,801- 125,500 83,701- 90,600 51,501- 55,700 6,250 125,501- 135,500 90,601- 97,900 55,701- 60,200 6,500 135,501- 145,800 97,901- 106,800 60,201 - 64,800 6,750 145,801- 156,700 106,801 - 113,200 64,801- 69,600 7,000 156,701- 167,900 113,201- 121,300 69,601- 74,600 7,250 167,901- 179,400 121,301 - 129,600 74,601- 79,800 7,500 179,401- 191,400 129,601 - 138,300 79,801- 85,100 7,750 - - 191,401- Greater 138,301- Greater 85,101- Greater 8,000 For SI: 1 square foot = 0.0929 m 1 gallon per minute = 3.785 Um, 1 pound per square inch = 6.895 kPa. a. The minimum required fire flow shall be allowed to be reduced by 25 percent for Group R. b. Types of construction are based on the International Building Code. c. Measured at 20 psi. 394 2006 INTERNATIONAL FIRE CODE® APPENDIX C FIRE HYDRANT LOCATIONS AND DISTRIBUTION The provisions contained in this appendix are not mandatory unless specifically referenced in the adopting ordinance. SECTION C101 SECTION C104 GENERAL CONSIDERATION OF EXISTING FIRE HYDRANTS C101.1 Scope. Fire hydrants shall be provided in accordance C104.1 Existing fire hydrants. Existing fire hydrants on pub - with this appendix for the protection of buildings, or portions lic streets are allowed to be considered as available. Existing of buildings, hereafter constructed. fire hydrants on adjacent properties shall not be considered available unless fire apparatus access roads extend between properties and easements are established to prevent obstruction SECTION C102 of such roads. LOCATION C102.1 Fire hydrant locations. Fire hydrants shall be pro- vided along required fire apparatus access roads and adjacent public streets. SECTION C105 DISTRIBUTION OF FIRE HYDRANTS SECTION C103 C105.1 Hydrant spacing. The average spacing between fire NUMBER OF FIRE HYDRANTS hydrants shall not exceed that listed in Table C105.1. C103.1 Fire hydrants available. The minimum number of fire Exception: The fire chief is authorized to accept a defi- hydrants available to a building shall not be less than that listed ciency of up to 10 percent where existing fire hydrants pro - in Table C105.1. The number of fire hydrants available to a vide all or a portion of the required fire hydrant service. complex or subdivision shall not be less than that determined by spacing requirements listed in Table C105.1 when applied Regardless of the average spacing, fire hydrants shall be to fire apparatus access roads and perimeter public streets from located such that all points on streets and access roads adjacent which fire operations could be conducted. to a building are within the distances listed in Table C105.1. TABLE C105.1 NUMBER AND DISTRIBUTION OF FIRE HYDRANTS AVERAGE SPACING MAXIMUM DISTANCE FROM FIRE -FLOW REQUIREMENT MINIMUM NUMBER BETWEEN HYDRANTSa' b. c ANY POINT ON STREET OR ROAD (gpm) OF HYDRANTS (feet) FRONTAGE TO A HYDRANT 1,750 or less 1 500 250 2,000 -2,250 2 450 225 2,500 3 450 225 3,000 3 400 225 3,500 -4,000 4 350 210 4,500 -5,000 5 300 180 5,500 6 300 180 6,000 6 250 150 6,500 -7,000 7 250 150 7,500 or more 8 or more 200 120 For SI: 1 foot = 304.8 mm, 1 gallon per minute = 3.785 IJm. a. Reduce by 100 feet for dead -end streets or roads. b. Where streets are provided with median dividers which can be crossed by fire fighters pulling hose lines, or where arterial streets are provided with four or more traffic lanes and have a traffic count of more than 30,000 vehicles per day, hydrant spacing shall average 500 feet on each side of the street and be arranged on an alternating basis up to a fire -flow requirement of 7,000 gallons per minute and 400 feet for higher fire -flow requirements. c. Where new water mains are extended along streets where hydrants are not needed for protection of structures or similar fire problems, fire hydrants shall be pro- vided at spacing not to exceed 1,000 feet to provide for transportation hazards. d. Reduce by 50 feet for dead -end streets or roads. e. One hydrant for each 1,000 gallons per minute or fraction thereof. 2006 INTERNATIONAL FIRE CODE® 395 APPENDIX D FIRE APPARATUS ACCESS ROADS The provisions contained in this appendix are not mandatory unless specifically referenced in the adopting ordinance. SECTION D101 D103.3 Turning radius. The minimum turning radius shall be GENERAL determined by the fire code official. D101.1 Scope. Fire apparatus access roads shall be in accor- D103.4 Dead ends. Dead -end fire apparatus access roads in dance with this appendix and all other applicable requirements excess of 150 feet (45 720 mm) shall be provided with width of the International Fire Code. and turnaround provisions in accordance with Table D103.4. TABLE D103.4 SECTION D102 REQUIREMENTS FOR DEAD -END FIRE REQUIRED ACCESS APPARATUS ACCESS ROADS D102.1 Access and loading. Facilities, buildings or portions LENGTH WIDTH g g p (feet) (feet) TURNAROUNDS REQUIRED of buildings hereafter constructed shall be accessible to fire department apparatus by way of an approved fire apparatus 0 -150 20 None required access road with an asphalt, concrete or other approved driving surface capable of supporting the imposed load of fire appara 120 foot Hammerhead, 60 foot "Y" or tus weighing at least 75,000 pounds (34 050 kg). 151 -500 20 96- foot - diameter cul -de -sac in accordance with Figure D103.1 120 -foot Hammerhead, 60 -foot "Y" or SECTION D103 501 -750 26 96- foot - diameter cul -de -sac in MINIMUM SPECIFICATIONS accordance with Figure D103.1 D103.1 Access road width with a hydrant. Where a fire Over 750 Special approval required hydrant is located on a fire apparatus access road, the minimum road width shall be 26 feet (7925 mm). See Figure D103.1. For SI: 1 foot = 304.8 mm. D103.2 Grade. Fire apparatus access roads shall not exceed 10 D103.5 Fire apparatus access road gates. Gates securing the percent in grade. fire apparatus access roads shall comply with all of the follow - Exception: Grades steeper than 10 percent as approved by ing criteria: the fire chief. 1. The minimum gate width shall be 20 feet (6096 mm). .0 � 20' 96' J '26' R 26' 28' R TYP.' 20 TYP.' 20' I 20' 26' 96' DIAMETER 60' "Y" MINIMUM CLEARANCE CUL -DE -SAC AROUND A FIRE HYDRANT 60'1 >h h60' NP 20'3 70' 28' R TYP.' 20'- 26' 20' 120' HAMMERHEAD ACCEPTABLE ALTERNATIVE TO 120' HAMMERHEAD For SI: 1 foot = 304.8 mm. FIGURE D103.1 DEAD -END FIRE APPARATUS ACCESS ROAD TURNAROUND 2006 INTERNATIONAL FIRE CODE® 397 APPENDIX D 2. Gates shall be of the swinging or sliding type. D104.2 Buildings exceeding 62,000 square feet in area. 3. Construction of gates shall be of materials that allow Buildings or facilities having a gross building area of more than manual operation by one person. 62,000 square feet (5760 m shall be provided with two sepa- rate and approved fire apparatus access roads. 4. Gate components shall be maintained in an operative condition at all times and replaced or repaired when Exception: Projects having a gross building area of up to defective. 124,000 square feet (11 520 m that have a single approved 5. Electric gates shall be equipped with a means of opening fire apparatus access road when all buildings are equipped the gate by fire department personnel for emergency throughout with approved automatic sprinkler systems. access. Emergency opening devices shall be approved D104.3 Remoteness. Where two access roads are re uired by the fire code official. q they shall be placed a distance apart equal to not less than one 6. Manual opening gates shall not be locked with a padlock half of the length of the maximum overall diagonal dimension or chain and padlock unless they are capable of being of the property or area to be served, measured in a straight line opened by means of forcible entry tools or when a key between accesses. box containing the key(s) to the lock is installed at the gate location. 7. Locking device specifications shall be submitted for approval by the fire code official. SECTION D105 D103.6 Signs. Where required by the fire code official, fire AERIAL FIRE APPARATUS ACCESS ROADS apparatus access roads shall be marked with permanent NO D105.1 Where required. Buildings or portions of buildings or PARKING —FIRE LANE signs complying with Figure facilities exceeding 30 feet (9144 mm) in height above the low - D103.6. Signs shall have a minimum dimension of 12 inches est level of fire department vehicle access shall be provided (305 mm) wide by 18 inches (457 mm) high and have red let- with approved fire apparatus access roads capable of accom- ters on a white reflective background. Signs shall be posted on modating fire department aerial apparatus. Overhead utility one or both sides of the fire apparatus road as required by Sec- and power lines shall not be located within the aerial fire appa- tion D103.6.1 or D103.6.2. ratus access roadway. SIGN TYPE "A" SIGN TYPE "C" SIGN TYPE "D„ D105.2 Width. Fire apparatus access roads shall have a mini- mum unobstructed width of 26 feet (7925 mm) in the immedi- NO NO NO ate vicinity of any building or portion of building more than 30 PARKING PARKING PARKING feet (9144 mm) in height. 18 " D105.3 Proximity to building. At least one of the required FIRE LANE FIRE LANE FIRE LANE I access routes meeting this condition shall be located within a .1■10. ♦" minimum of 15 feet (4572 mm) and a maximum of 30 feet (9144 mm) from the building, and shall be positioned parallel — 12" . = 12" 12" ----I to one entire side of the building. FIGURE D103.6 FIRE LANE SIGNS SECTION D106 MULTIPLE - FAMILY RESIDENTIAL DEVELOPMENTS D103.6.1 Roads 20 to 26 feet in width. Fire apparatus D106.1 Projects having more than 100 dwelling units. Mul- access roads 20 to 26 feet wide (6096 to 7925 mm) shall be tiple- family residential projects having more than 100 dwell - posted on both sides as a fire lane. ing units shall be equipped throughout with two separate and D103.6.2 Roads more than 26 feet in width. Fire appara- approved fire apparatus access roads. tus access roads more than 26 feet wide (7925 mm) to 32 feet wide (9754 mm) shall be posted on one side of the road Exception: Projects having up to 200 dwelling units may as a fire lane. have a single approved fire apparatus access road when all buildings, including nonresidential occupancies, are equipped throughout with approved automatic sprinkler systems installed in accordance with Section 903.3.1.1 or SECTION D104 903.3.1.2. COMMERCIAL AND INDUSTRIAL DEVELOPMENTS D106.2 Projects having more than 200 dwelling units. Mul- D104.1 Buildings exceeding three stories or 30 feet in tiple - family residential projects having more than 200 dwell- height. Buildings or facilities exceeding 30 feet (9144 mm) or ing units shall be provided with two separate and approved fire three stories in height shall have at least three means of fire apparatus access roads regardless of whether they are equipped apparatus access for each structure. with an approved automatic sprinkler system. 398 2006 INTERNATIONAL FIRE CODE® APPENDIX D SECTION D107 ONE- OR TWO- FAMILY RESIDENTIAL DEVELOPMENTS D107.1 One- or two - family dwelling residential develop- ments. Developments of one- or two - family dwellings where the number of dwelling units exceeds 30 shall be provided with separate and approved fire apparatus access roads and shall meet the requirements of Section D104.3. Exceptions: 1. Where there are more than 30 dwelling units on a sin- gle public or private fire apparatus access road and all dwelling units are equipped throughout with an approved automatic sprinkler system in accordance with Section 903.3.1.1, 903.3.1.2 or 903.3.1.3.3, access from two directions shall not be required. 2. The number of dwelling units on a single fire appara- tus access road shall not be increased unless fire appa- ratus access roads will connect with future development, as determined by the fire code official. 2006 INTERNATIONAL FIRE CODE® 399 APPENDIX E HAZARD CATEGORIES This appendix is for information purposes and is not intended for adoption. SECTION E101 Test methods or guidelines for hazard classification of ener- GENERAL getic materials used for in- process operations shall be E101.1 Scope. This appendix provides information, explana- approved by the fire code official. Test methods used shall tions and examples to illustrate and clarify the hazard catego be DOD, BATF, UN/DOT or other approved criteria. The ries contained in Chapter 27 of the International Fire Code. results of such testing shall become a portion of the files of The hazard categories are based upon the DOL 29 CFR. Where the jurisdiction and be included as an independent section of numerical classifications are included, they are in accordance any Hazardous Materials Management Plan (HMMP) with nationally recognized standards. required by Section 3305.2.1. Also see Section 104.7.2. This appendix should not be used as the sole means of haz- Examples of materials in various Divisions are as fol- ardous materials classification. lows: 1. Division 1.1 (High Explosives). Consists of explo- SECTION E102 sives that have a mass explosion hazard. A mass HAZARD CATEGORIES explosion is one which affects almost the entire pile of material instantaneously. Includes substances that, E102.1 Physical hazards. Materials classified in this section when tested in accordance with approved methods, pose a physical hazard. can be caused to detonate by means of a blasting cap E102.1.1 Explosives and blasting agents. The current when unconfined or will transition from deflagration UN/DOT classification system recognized by international to a detonation when confined or unconfined. Exam authorities, the Department of Defense and others classifies pies: dynamite, TNT, nitroglycerine, C-3, HMX, all explosives as Class 1 materials. They are then divided RDX, encased explosives, military ammunition. into six separate divisions to indicate their relative hazard. 2. Division 1.2 (Low Explosives). Consists of explo- There is not a direct correlation between the designations sives that have a projection hazard, but not a mass used by the old DOT system and those used by the current explosion hazard. Examples: nondetonating encased system nor is there correlation with the system (high and explosives, military ammunition and the like. low) established by the Bureau of Alcohol, Tobacco and 3. Division 1.3 (Low Explosives). Consists of explo- Firearms (BATF). Table 3304.3 provides some guidance sives that have a fire hazard and either a minor blast with regard to the current categories and their relationship to hazard or a minor projection hazard or both, but not a the old categories. Some items may appear in more than one mass explosion hazard. The major hazard is radiant division, depending on factors such as the degree of con- heat or violent burning, or both. Can be deflagrated finement or separation, by type of packaging, storage con when confined. Examples: smokeless powder, pro figuration or state of assembly. pellant explosives, display fireworks. In order to determine the level of hazard presented by 4. Division 1.4. Consists of explosives that pose a minor explosive materials, testing to establish quantitatively their explosion hazard. The explosive effects are largely explosive nature is required. There are numerous test meth confined to the package and no projection of frag- ods that have been used to establish the character of an ments of appreciable size or range is expected. An explosive material. Standardized tests, required for finished internal fire must not cause virtually instantaneous goods containing explosives or explosive materials in a explosion of almost the entire contents of the pack - packaged form suitable for shipment or storage, have been established by UN/DOT and BATF. However, these tests do age. Examples: squibs (nondetonating igniters), not consider key elements that should be examined in a explosive actuators, explosive trains (low level deto- manufacturing situation. In manufacturing operations, the rating cord). condition and/or the state of a material may vary within the 5. Division 1.5 (Blasting Agents). Consists of very process. The in- process material classification and classifi- insensitive explosives. This division is comprised of cation requirements for materials used in the manufacturing substances which have a mass explosion hazard, but process may be different from the classification of the same are so insensitive that there is very little probability of material when found in finished goods depending on the initiation or of transition from burning to detonation stage of the process in which the material is found. A classi- under normal conditions of transport. Materials are fication methodology must be used that recognizes the haz- not cap sensitive; however, they are mass detonating ards commensurate with the application to the variable when provided with sufficient input. Examples: oxi- physical conditions as well as potential variations of physi- dizer and liquid fuel slurry mixtures and gels, ammo - cal character and type of explosive under consideration. nium nitrate combined with fuel oil. 2006 INTERNATIONAL FIRE CODE® 401 APPENDIX E 6. Division 1.6. Consists of extremely insensitive arti- 2. Combustible liquids. cles which do not have a mass explosive hazard. This Class II liquids shall include those having flash division is comprised of articles which contain only points at or above 100 °F (38 °C) and below 140 °F extremely insensitive detonating substances and (60 °C). which demonstrate a negligible probability of acci- dental initiation or propagation. Although this cate- Class IIIA liquids shall include those having flash gory of materials has been defined, the primary points at or above 140 °F (60 °C) and below 200 °F application is currently limited to military uses. (93 °C). Examples: Low vulnerability military weapons. Class IIIB liquids shall include those liquids hav- Explosives in each division are assigned a compatibility ing flash points at or above 200 °F (93 °C). group letter by the Associate Administrator for Hazardous E102.1.4 Flammable solids. Examples include: Materials Safety (DOT) based on criteria specified by DOTn 49CFR. Compatibility group letters are used to spec- 1. Organic solids: camphor, cellulose nitrate, naphtha - ify the controls for the transportation and storage related to lene. various materials to prevent an increase in hazard that might 2. Inorganic solids: decaborane, lithium amide, phos- result if certain types of explosives were stored or trans- phorous heptasulfide, phosphorous sesquisulfide, ported together. Altogether, there are 35 possible classifica- potassium sulfide, anhydrous sodium sulfide, sulfur. tion codes for explosives, e.g., 1.1A, 1.3C, 1.4S, etc. 3. Combustible metals (except dusts and powders): E102.1.2 Compressed gases. Examples include: cesium, magnesium, zirconium. 1. Flammable: acetylene, carbon monoxide, ethane, eth- E102.1.5 Combustible dusts and powders. Finely divided ylene, hydrogen, methane. Ammonia will ignite and solids which may be dispersed in air as a dust cloud: wood burn although its flammable range is too narrow for it sawdust, plastics, coal, flour, powdered metals (few excep- to fit the definition of flammable gas. tions). 2. Oxidizing: oxygen, ozone, oxides of nitrogen, chlo- E102.1.6 Combustible fibers. See Section 2902.1. rine and fluorine. Chlorine and fluorine do not contain oxygen but reaction with flammables is similar to that E102.1.7 Oxidizers. Examples include: of oxygen. 1. Gases: oxygen, ozone, oxides of nitrogen, fluorine 3. Corrosive: ammonia, hydrogen chloride, fluorine. and chlorine (reaction with flammables is similar to 4. Highly toxic: arsine, cyanogen, fluorine, germane, that of oxygen). hydrogen cyanide, nitric oxide, phosphine, hydrogen 2. Liquids: bromine, hydrogen peroxide, nitric acid, selenide, stibine. perchloric acid, sulfuric acid. 5. Toxic: chlorine, hydrogen fluoride, hydrogen sulfide, 3. Solids: chlorates, chromates, chromic acid, iodine, phosgene, silicon tetrafluoride. nitrates, nitrites, perchlorates, peroxides. 6. Inert (chemically unreactive): argon, helium, kryp- E102.1.7.1 Examples of liquid and solid oxidizers ton, neon, nitrogen, xenon. according to hazard. 7. Pyrophoric: diborane, dichloroborane, phosphine, Class 4: ammonium perchlorate (particle size greater silane. than 15 microns), ammonium permanganate, 8. Unstable (reactive): butadiene (unstabilized), ethyl- guanidine nitrate, hydrogen peroxide solutions more ene oxide, vinyl chloride. than 91 percent by weight, perchloric acid solutions more than 72.5 percent by weight, potassium E102.1.3 Flammable and combustible liquids. Examples superoxide, tetranitromethane. include: Class 3: ammonium dichromate, calcium 1. Flammable liquids. hypochlorite (over 50 percent by weight), chloric acid Class IA liquids shall include those having flash (10 percent maximum concentration), hydrogen per - points below 73 °F (23 °C) and having a boiling oxide solutions (greater than 52 percent up to 91 per - point at or below 100 °F (38 °C). cent), mono - (trichloro)- tetra- (monopotassium Class IB liquids shall include those having flash dichloro) - penta- s- triazinetrione, nitric acid, (fuming points below 73 °F (23 °C) and having a boiling —more than 86 percent concentration), perchloric point at or above 100 °F (38 °C). acid solutions (60 percent to 72 percent by weight), potassium bromate, potassium chlorate, potassium Class IC liquids shall include those having flash dichloro -s- triazinetrione (potassium dichloro- points at or above 73 °F (23 °C.) and below 100 °F isocyanurate), sodium bromate, sodium chlorate, (38 °C). sodium chlorite (over 40 percent by weight) and 402 2006 INTERNATIONAL FIRE CODE() . APPENDIX E sodium dichloro- s- triazinetrione (sodium dichloro- hydroperoxide 90 percent, t -butyl peroxyacetate 75 isocyanurate). percent, t -butyl peroxyisopropylcarbonate 92 per - Class 2: barium bromate, barium chlorate, barium cent, diisopropyl peroxydicarbonate 100 percent, hypochlorite, barium perchlorate, barium permanga di n propyl peroxydicarbonate 98 percent, and nate, 1- bromo -3- chloro -5, 5- dimethylhydantoin, cal- di n propyl peroxydicarbonate 85 percent. cium chlorate, calcium chlorite, calcium hypochlorite Class II: acetyl peroxide 25 percent, t -butyl (50 percent or less by weight), calcium perchlorate, hydroperoxide 70 percent (with DTBP and t -BuOH calcium permanganate, chromium trioxide (chromic diluents), t -butyl peroxybenzoate 98 percent, t -butyl acid), copper chlorate, halane (1, 3- dichloro -5, peroxy -2- ethylhexanoate 97 percent, t -butyl 5- dimethylhydantoin), hydrogen peroxide (greater peroxyisobutyrate 75 percent, t -butyl than 27.5 percent up to 52 percent), lead perchlorate, peroxyisopropyl - carbonate 75 percent, t -butyl lithium chlorate, lithium hypochlorite (more than 39 peroxypivalate 75 percent, dybenzoyl percent available chlorine), lithium perchlorate, mag- peroxydicarbonate 85 percent, di- sec -butyl nesium bromate, magnesium chlorate, magnesium peroxydicarbonate 98 percent, di- sec -butyl perchlorate, mercurous chlorate, nitric acid (more peroxydicarbonate 75 percent, than 40 percent but less than 86 percent), perchloric 1,1- di- (t- butylperoxy)- 3,5,5 - trimethyecyclohexane acid solutions (more than 50 percent but less than 60 95 percent, di- (2- ethythexyl) peroxydicarbonate 97 percent), potassium perchlorate, potassium per- percent, 2,5- dymethyl -2 -5 di (benzoylperoxy) hex - manganate, potassium peroxide, potassium ane 92 percent, and peroxyacetic acid 43 percent. superoxide, silver peroxide, sodium chlorite (40 per- Class III: acetyl cyclohexane sulfonal peroxide 29 cent or less by weight), sodium perchlorate, sodium percent, benzoyl peroxide 78 percent, benzoyl perox- perchlorate monohydrate, sodium permanganate, ide paste 55 percent, benzoyl peroxide paste 50 per - sodium peroxide, strontium chlorate, strontium per- cent peroxide /50 percent butylbenzylphthalate chlorate, thallium chlorate, trichloro -s- triazinetrione diluent, cumene hydroperoxide 86 percent, (trichloroisocyanuric acid), urea hydrogen peroxide, di- (4- butylcyclohexyl) peroxydicarbonate 98 per - zinc bromate, zinc chlorate and zinc permanganate. cent, t -butyl peroxy -2- ethylhexanoate 97 percent, Class 1: all inorganic nitrates (unless otherwise classi- t -butyl peroxyneodecanoate 75 percent, decanoyl fied), all inorganic nitrites (unless otherwise classi- peroxide 98.5 percent, di -t -butyl peroxide 99 percent, fied), ammonium persulfate, barium peroxide, 1,1- di- (t- butylperoxy )3,5,5- trimethylcyclohexane75 calcium peroxide, hydrogen peroxide solutions percent, 2,4- dichlorobenzoyl peroxide 50 percent, (greater than 8 percent up to 27.5 percent), lead diox- diisopropyl peroxydicarbonate 30 percent, ide, lithium hypochlorite (39 percent or less available 2,-5-dimethyl-2,5-di-(2- ethylhexanolyperoxy) -hex- chlorine), lithium peroxide, magnesium peroxide, ane 90 percent, 2, 5- dimethyl- 2,5- di -(t- butylperoxy) manganese dioxide, nitric acid (40 percent concentra- hexane 90 percent and methyl ethyl ketone peroxide 9 tion or less), perchloric acid solutions (less than 50 percent active oxygen diluted in dimethyl phthalate. percent by weight), potassium dichromate, potassium Class IV: benzoyl peroxide 70 percent, benzoyl per - percarbonate, potassium persulfate, sodium carbon- oxide paste 50 percent peroxide /15 percent water /35 ate peroxide, sodium dichloro -s- triazinetrione percent butylphthalate diluent, benzoyl peroxide dihydrate, sodium dichromate, sodium perborate slurry 40 percent, benzoyl peroxide powder 35 per - (anhydrous), sodium perborate monohydrate, sodium cent, t -butyl hydroperoxide 70 percent, (with water perborate tetrahydrate, sodium percarbonate, sodium diluent), t -butyl peroxy -2- ethylhexanoate 50 percent, persulfate, strontium peroxide and zinc peroxide. decumyl peroxide 98 percent, di- (2- ethylhexal) E102.1.8 Organic peroxides. Organic peroxides contain peroxydicarbonate 40 percent, laurel peroxide 98 per - the double oxygen or peroxy ( -o -o) group. Some are flam- cent, p- methane hydroperoxide 52.5 percent, methyl mable compounds and subject to explosive decomposition. ethyl ketone peroxide 5.5 percent active oxygen and They are available as: methyl ethyl ketone peroxide 9 percent active oxygen 1. Liquids. diluted in water and glycols. 2. Pastes. Class V: benzoyl peroxide 35 percent, 1,1 -di -t -butyl peroxy 3,5,5 - trimethylcyclohexane 40 percent, 3. Solids (usually finely divided powers). 2,5 -di -(t -butyl peroxy) hexane 47 percent and E102.1.8.1 Classification of organic peroxides 2,4- pentanedione peroxide 4 percent active oxygen. according to hazard. E102.1.9 Pyrophoric materials.Examples include: Unclassified: Unclassified organic peroxides are 1. Gases: diborane, phosphine, silane. capable of detonation and are regulated in accordance 2. Liquids: diethylaluminum chloride, di- with Chapter 33. ethylberyllium, diethylphosphine, diethylzinc, Class I: acetyl cyclohexane sulfonyl 60 -65 percent dimethylarsine, triethylaluminum etherate, tri- concentration by weight, fulfonyl peroxide, benzoyl ethylbismuthine, triethylboron, trimethylaluminum, peroxide over 98 percent concentration, t -butyl trimethylgallium. 2006 INTERNATIONAL FIRE CODE 403 APPENDIX E 3. Solids: cesium, hafnium, lithium, white or yellow (mercuric bromide), mercury (II) chloride (corrosive phosphorous, plutonium, potassium, rubidium, mercury chloride), pentachlorophenol, methyl para- sodium, thorium. thion, phosphorus (white) and sodium azide. E102.1.10 Unstable (reactive) materials. Examples E102.2.2 Toxic materials. Examples include: include: 1. Gases: boron trichloride, boron trifluoride, chlorine, Class 4: acetyl peroxide, dibutyl peroxide, dinitroben- chlorine trifluoride, hydrogen fluoride, hydrogen sul- zene, ethyl nitrate, peroxyacetic acid and picric acid fide, phosgene, silicon tetrafluoride. (dry) trinitrobenzene. 2. Liquids: acrylonitrile, allyl alcohol, Class 3: hydrogen peroxide (greater than 52 percent), alpha - chlorotoluene, aniline, 1- chloro- hydroxylamine, nitromethane, paranitroaniline, 2,3- epoxypropane, chloroformic acid (allyl ester), perchloric acid and tetrafluoroethylene monomer. 3- chloropropene ( alkyl chloride), o- cresol, Class 2: acrolein, acrylic acid, hydrazine, methacrylic crotonaldehyde, dibromomethane, acid, sodium perchlorate, styrene and vinyl acetate. diisopropylamine, diethyl ester sulfuric acid, dimethyl ester sulfuric acid, 2- furaldehyde ( furfural), Class 1: acetic acid, hydrogen peroxide 35 percent to 52 furfural alcohol, phosphorus chloride, phosphoryl percent, paraldehyde and tetrahydrofuran. chloride (phosphorus oxychloride) and thionyl chlo- E102.1.11 Water- reactive materials. Examples include: ride. Class 3: aluminum alkyls such as triethylaluminum, 3. Solids: acrylamide, barium chloride, barium (II) isobutylaluminum and trimethylaluminum; bromine nitrate, benzidine, p- benzoquinone, beryllium chlo- pentafluoride, bromine trifluoride, ride, cadmium chloride, cadmium oxide, chloroacetic chlorodiethylaluminium and diethylzinc. acid, chlorophenylmercury (phenyl mercuric chlo- Class 2: calcium carbide, calcium metal, cyanogen bro- ride), chromium (VI) oxide (chromic acid, solid), 2,4- mide, lithium hydride, methyldichlorosilane, potassium dinitrotoluene, hydroquinone, mercury chloride (cal metal, potassium peroxide, sodium metal, sodium perox omel), mercury (II) sulfate (mercuric sulfate), ide, sulfuric acid and trichlorosilane. osmium tetroxide, oxalic acid, phenol, P- phenylenediamine, phenylhydrazine, Class 1: acetic anhydride, sodium hydroxide, sulfur 4- phenylmorpholine, phosphorus sulfide, potassium monochloride and titanium tetrachloride. fluoride, potassium hydroxide, selenium (IV) E102.1.12 Cryogenic fluids. The cryogenics listed will disulfide and sodium fluoride. exist as compressed gases when they are stored at ambient E102.2.3 Corrosives. Examples include: temperatures. 1. Acids: Examples: chromic, formic, hydrochloric 1. Flammable: carbon monoxide, deuterium (heavy (muriatic) greater than 15 percent, hydrofluoric, nitric hydrogen), ethylene, hydrogen, methane. (greater than 6 percent, perchloric, sulfuric (4 percent 2. Oxidizing: fluorine, nitric oxide, oxygen. or more). 3. Corrosive: fluorine, nitric oxide. 2. Bases (alkalis): hydroxides — ammonium (greater 4. Inert (chemically unreactive): argon, helium, kryp- than 10 percent), calcium, potassium (greater than 1 ton, neon, nitrogen, xenon. percent), sodium (greater than 1 percent); certain car- bonates— potassium. 5. Highly toxic: fluorine, nitric oxide. 3. Other corrosives: bromine, chlorine, fluorine, iodine, E102.2 Health hazards. Materials classified in this section ammonia. pose a health hazard. Note: Corrosives that are oxidizers, e.g., nitric acid, E102.2.1 Highly toxic materials. Examples include: chlorine, fluorine; or are compressed gases, e.g., ammo- 1. Gases: arsine, cyanogen, diborane, fluorine, ger- nia, chlorine, fluorine; or are water - reactive, e.g., con - mane, hydrogen c cyanide, nitric oxide, nitrogen diox- centrated sulfuric acid, sodium hydroxide, are physical y g ide, ozone, phosphine, hydrogen selenide, stibine. hazards in addition to being health hazards. 2. Liquids: acrolein, acrylic acid, 2- chloroethanol (eth- ylene chlorohydrin), hydrazine, hydrocyanic acid, SECTION E103 2- methylaziridine (propylenimine), EVALUATION OF HAZARDS 2- methylacetonitrile (acetone cyanohydrin), methyl ester isocyanic acid (methyl isocyanate), nicotine, E103.1 Degree of hazard. The degree of hazard present tetranitromethane and tetraethylstannane depends on many variables which should be considered indi- (tetraethyltin). vidually and in combination. Some of these variables are as 3. Solids: (aceto) phenylmercury (phenyl mercuric ace- shown in Sections E103.1.1 through E103.1.5. tate), 4- aminopyridine, arsenic pentoxide, arsenic tri- E103.1.1 Chemical properties of the material. Chemical oxide, calcium cyanide, 2- chloroacetophenone, ro erties of the material determine self reactions and reac- P P aflatoxin B, decaborane(14), mercury (II) bromide tions which may occur with other materials. Generally, 404 2006 INTERNATIONAL FIRE CODE® APPENDIX E materials within subdivisions of hazard categories will LC 50m = [C / LC (Equation E - exhibit similar chemical properties. However, materials ] with similar chemical properties may pose very different For multi- component mixtures where more than one hazards. Each individual material should be researched to component has a listed LC the LC50 of the mixture is determine its hazardous properties and then considered in estimated by use of the following formula: relation to other materials that it might contact and the sur- rounding environment. 1 C 50m – C /L C. / /L E103.1.2 Physical properties of the material. Physical ( u Sorg) + ( �z so;z) + ( C �n s ) properties, such as whether a material is a solid, liquid or gas (Equation E -2) at ordinary temperatures and pressures, considered along with chemical properties will determine requirements for where: containment of the material. Specific gravity (weight of a liquid compared to water) and vapor density (weight of a gas LC LC of the mixture in parts per million (ppm). compared to air) are both physical properties which are C, = concentration of component (i) in decimal per - important in evaluating the hazards of a material. cent. The concentration of the individual com- ponents in a mixture of gases is to be expressed E103.1.3 Amount and concentration of the material. The in terms of percent by volume. amount of material present and its concentration must be considered along with physical and chemical properties to LC = LC of component (i). The LC of the compo- determine the magnitude of the hazard. Hydrogen peroxide, nent is based on a 1 -hour exposure. LC50 data for example, is used as an antiseptic and a hair bleach in low which are for other than 1-hour exposures shall concentrations (approximately 8 percent in water solution). be normalized to 1-hour by multiplying the Over 8 percent, hydrogen peroxide is classed as an oxidizer LC for the time determined by the factor indi and is toxic. Above 90 percent, it is a Class 4 oxidizer "that Gated in Table E103.1.3.1. The preferred mam- can undergo an explosive reaction when catalyzed or malian species for LC50 data is the rat, as exposed to heat, shock or friction," a definition which inci specified in the definitions of toxic and highly dentally also places hydrogen peroxide over 90- percent toxic in Chapter 2 of the International Fire concentration in the unstable (reactive) category. Small Code. If data for rats are unavailable, and in the amounts at high concentrations may present a greater haz absence of information to the contrary, data for and than large amounts at low concentrations. other species may be utilized. The data shall be taken in the following order of preference: rat, E103.1.3.1 Mixtures. Gases —toxic and highly toxic mouse, rabbit, guinea pig, cat, dog, monkey. gases include those gases which have an LC of 2,000 i = component 1, component 2 and so on to the nth parts per million (ppm) or less when rats are exposed for component. a period of 1 hour or less. To maintain consistency with the definitions for these materials, exposure data for peri- Examples: ods other than 1 hour must be normalized to 1 hour. To a. What is the LC of a mixture of 15- percent chlorine, classify mixtures of compressed gases that contain one 85- percent nitrogen? or more toxic or highly toxic components, the LC of the mixture must be determined. Mixtures that contain only The 1 -hour (rat) LC of pure chlorine is 293 ppm. two components are binary mixtures. Those that contain LC50m = 1 / (0.15 / 293) or 1,953 ppm. Therefore, the more than two components are multi- component mix- mixture is toxic. tures. When two or more hazardous substances (compo- nents) having an LC below 2,000 ppm are present in a b. What is the LC of a mixture of 15- percent chlorine, mixture, their combined effect, rather than that of the 15 percent fluorine and 70- percent nitrogen? The individual substances (components), must be consid 1-hour (rat) LC of chlorine is 293 ppm. The 1 -hour ered. In the absence of information to the contrary, the (rat) LC of fluorine is 185 ppm. effects of the hazards present must be considered as addi- LC = 1 / (0.15 / 293) + (0.15 / 185) or 755 ppm. tive. Exceptions to the above rule may be made when Therefore the mixture is toxic. there is a good reason to believe that the principal effects c. Is the mixture of 1 percent phosphine in argon toxic or of the different harmful substances (components) are not highly toxic? The 1 -hour (rat) LC is 11 ppm. additive. LCs0m = 1 / [0.01 / (11 2)] or 2,200 ppm. Therefore For binary mixtures where the hazardous component the mixture is neither toxic nor highly toxic. is diluted with a nontoxic gas such as an inert gas, the Note that the 4 -hour LC of 11 ppm was nor - LC of the mixture is estimated by use of the following malized to 1 -hour by use of Section formula: E103.1.3.1. 2006 INTERNATIONAL FIRE CODE 405 APPENDIX E TABLE E103.1.3.1 8. How does the activity impact the hazardous character - NORMALIZATION FACTOR istics of the material? Consider vapors released or haz- TIME (hours) MULTIPLY BY ards otherwise exposed. 0.5 0.7 9. What must the material be protected from? Consider 1.0 1.0 other materials, temperature, shock, pressure, etc. 1.5 1.2 10. What effects of the material must people and the envi- ronment be protected from? 2.0 1.4 11. How can protection be accomplished? Consider: 3.0 1.7 11.1. Proper containers and equipment. 4.0 2.0 11.2. Separation by distance or construction. 5.0 2.2 11.3. Enclosure in cabinets or rooms. 6.0 2.4 11.4. Spill control, drainage and containment. 7.0 2.6 11.5. Control systems - ventilation, special electri- 8.0 2.8 cal, detection and alarm, extinguishment, E103.1.4 Actual use, activity or process involving the explosion venting, limit controls, exhaust scrubbers and excess flow control. material. The definition of handling, storage and use in closed systems refers to materials in packages or containers. 11.6. Administrative (operational) controls- signs, Dispensing and use in open containers or systems describes ignition source control, security, personnel situations where a material is exposed to ambient conditions training, established procedures, storage plans or vapors are liberated to the atmosphere. Dispensing and and emergency plans. use in open systems, then, are generally more hazardous sit- Evaluation of the hazard is a strongly subjec- uations than handling, storage or use in closed systems. The tive process; therefore, the person charged with actual use or process may include heating, electric or other this responsibility must gather as much relevant sparks, catalytic or reactive materials and many other fac- data as possible so that the decision will be tors which could affect the hazard and must therefore be objective and within the limits prescribed in thoroughly analyzed. laws, policies and standards. E103.1.5 Surrounding conditions. Conditions such as It may be necessary to cause the responsible other materials or processes in the area, type of construction persons in charge to have tests made by support persons or testing laboratories to support of the structure, fire protection features (e.g., fire walls, contentions that a particular material or process sprinkler systems, alarms, etc.), occupancy (use) of adjoin- is or is not hazardous. See Section 104.7.2 of ing areas, normal temperatures, exposure to weather, etc., the International Fire Code. must be taken into account in evaluating the hazard. E103.2 Evaluation questions. The following are sample eval- uation questions: 1. What is the material? Correct identification is impor- tant; exact spelling is vital. Check labels, MSDS, ask responsible persons, etc. 2. What are the concentration and strength? 3. What is the physical form of the material? Liquids, gases and finely divided solids have differing require- ments for spill and leak control and containment. 4. How much material is present? Consider in relation to permit amounts, maximum allowable quantity per con- trol area (from Group H occupancy requirements), amounts which require detached storage and overall magnitude of the hazard. 5. What other materials (including furniture, equipment and building components) are close enough to interact with the material? 6. What are the likely reactions? 7. What is the activity involving the material? 406 2006 INTERNATIONAL FIRE CODE® APPENDIX F HAZARD RANKING The provisions contained in this appendix are not mandatory unless specifically referenced in the adopting ordinance. SECTION F101 GENERAL F101.1 Scope. Assignment of levels of hazards to be applied to specific hazard classes as required by NFPA 704 shall be in accordance with this appendix. The appendix is based on appli- cation of the degrees of hazard as defined in NFPA 704 arranged by hazard class as for specific categories defined in Chapter 2 of the International Fire Code and used throughout. F101.2 General. The hazard rankings shown in Table F101.2 have been established by using guidelines found within NFPA 704. As noted in Section 4.2 of NFPA 704, there could be spe- cific reasons to alter the degree of hazard assigned to a specific material; for example, ignition temperature, flammable range or susceptibility of a container to rupture by an internal com- bustion explosion or to metal failure while under pressure or because of heat from external fire. As a result, the degree of hazard assigned for the same material can vary when assessed by different people of equal competence. The hazard rankings assigned to each class represent reason- able minimum hazard levels for a given class based on the use of criteria established by NFPA 704. Specific cases of use or storage may dictate the use of higher degrees of hazard in cer- tain cases. SECTION F102 REFERENCED STANDARDS ICC IFC International Fire Code F101.1 NFPA 704 Identification of the F101.1, F101.2 Hazards of Materials for Emergency Response 2006 INTERNATIONAL FIRE CODE® 407 APPENDIX F TABLE F101.2 FIRE FIGHTER WARNING PLACARD DESIGNATIONS BASED ON HAZARD CLASSIFICATION CATEGORIES HAZARD CATEGORY DESIGNATION Combustible liquid II F2 Combustible liquid IIIA F2 Combustible liquid IIIB Fl Combustible dust F4 Combustible fiber F3 Cryogenic flammable F4, H3 Cryogenic oxidizing OX, H3 Explosive R4 Flammable solid F2 Flammable gas (gaseous) F4 Flammable gas (liquefied) F4 Flammable liquid IA F4 Flammable liquid IB F3 Flammable liquid IC F3 Organic peroxide, UD R4 Organic peroxide I F4, R3 Organic peroxide II F3, R3 Organic peroxide III F2, R2 Organic peroxide IV Fl, RI Organic peroxide V Nonhazard Oxidizing gas (gaseous) OX Oxidizing gas (liquefied) OX Oxidizer 4 OX Oxidizer 3 OX Oxidizer 2 OX Pyrophoric gases F4 Pyrophoric solids, liquids F3 Unstable reactive 4D R4 Unstable reactive 3D R4 Unstable reactive 3N R3 Unstable reactive 2 R2 Water reactive 3 W, R3 Water reactive 2 W, R2 Corrosive H3, COR Toxic H3 Highly toxic H4 F— Flammable category. COR— Corrosive. R— Reactive category. UD— Unclassified detonable material. H— Health category. 4D—Class 4 detonable material. W— Special hazard: water reactive. 3D —Class 3 detonable material. OX— Special hazard: oxidizing properties. 3N —Class 3 nondetonable material. 408 2006 INTERNATIONAL FIRE CODE® APPENDIX G CRYOGENIC FLUIDS - WEIGHT AND VOLUME EQUIVALENTS This appendix is for information purposes and is not intended for adoption. SECTION G101 GENERAL G101.1 Scope. This appendix is used to convert from liquid to gas for cryogenic fluids. G101.2 Conversion. Table G101.2 shall be used to determine the equivalent amounts of cryogenic fluids in either the liquid or gas phase. G101.2.1 Use of the table. To use Table G101.2, read hori- zontally across the line of interest. For example, to deter- mine the number of cubic feet of gas contained in 1.0 gallon (3.785 L) of liquid argon, find 1.000 in the column entitled "Volume of Liquid at Normal Boiling Point." Reading across the line under the column entitled "Volume of Gas at 70 °F and 1 atmosphere 14.7 psia," the value of 112.45 cubic feet (3.184 m is found. G101.2.2 Other quantities. If other quantities are of inter- est, the numbers obtained can be multiplied or divided to obtain the quantity of interest. For example, to determine the number of cubic feet of argon gas contained in a volume of 1,000 gallons (3785 L) of liquid argon at its normal boiling point, multiply 112.45 by 1,000 to obtain 112,450 cubic feet (3184 m 2006 INTERNATIONAL FIRE CODE 409 APPENDIX G TABLE G101.2 WEIGHT AND VOLUME EQUIVALENTS FOR COMMON CRYOGENIC FLUIDS VOLUME OF LIQUID AT NORMAL CRYOGENIC WEIGHT OF LIQUID OR GAS BOILING POINT VOLUME OF GAS AT NTP FLUID Pounds Kilograms Liters Gallons Cubic feet Cubic meters 1.000 0.454 0.326 0.086 9.67 0.274 2.205 1.000 0.718 0.190 21.32 0.604 Argon 3.072 1.393 1.000 0.264 29.71 0.841 11.628 5.274 3.785 1.000 112.45 3.184 10.340 4.690 3.366 0.889 100.00 2.832 3.652 1.656 1.189 0.314 35.31 1.000 1.000 0.454 3.631 0.959 96.72 2.739 2.205 1.000 8.006 2.115 213.23 6.038 Helium 0.275 0.125 1.000 0.264 26.63 0.754 1.042 0.473 3.785 1.000 100.82 2.855 1.034 0.469 3.754 0.992 100.00 2.832 0.365 0.166 1.326 0.350 35.31 1.000 1.000 0.454 6.409 1.693 191.96 5.436 2.205 1.000 14.130 3.733 423.20 11.984 Hydrogen 0.156 0.071 1.000 0.264 29.95 0.848 0.591 0.268 3.785 1.000 113.37 3.210 0.521 0.236 3.339 0.882 100.00 2.832 0.184 0.083 1.179 0.311 35.31 1.000 1.000 0.454 0.397 0.105 12.00 0.342 2.205 1.000 0.876 0.231 26.62 0.754 Oxygen 2.517 1.142 1.000 0.264 30.39 0.861 9.527 4.321 3.785 1.000 115.05 3.250 8.281 3.756 3.290 0.869 100.00 2.832 2.924 1.327 1.162 0.307 35.31 1.000 1.000 0.454 0.561 0.148 13.80 0.391 2.205 1.000 1.237 0.327 30.43 0.862 Nitrogen 1.782 0.808 1.000 0.264 24.60 0.697 6.746 3.060 3.785 1.000 93.11 2.637 7.245 3.286 4.065 1.074 100.00 2.832 2.558 1.160 1.436 0.379 35.31 1.000 1.000 0.454 1.052 0.278 22.968 0.650 2.205 1.000 2.320 0.613 50.646 1.434 LNG' 0.951 0.431 1.000 0.264 21.812 0.618 3.600 1.633 3.785 1.000 82.62 2.340 4.356 1.976 4.580 1.210 100.00 2.832 11.501 5.217 1.616 0.427 35.31 1.000 For SI: 1 pound = 0.454 kg, 1 gallon = 3.785 L, 1 cubic foot = 0.02832 m °C = [( °F)- 32]/1.8, 1 pound per square inch atmosphere = 6.895 kPa. a. The values listed for liquefied natural gas (LNG) are "typical" values. LNG is a mixture of hydrocarbon gases, and no two LNG streams have exactly the same composition. 410 2006 INTERNATIONAL FIRE CODE®